The discoloration of gold, sometimes manifesting as a greenish hue on jewelry or other gold objects, is a phenomenon primarily associated with the presence of other metals in the alloy. Pure gold, being chemically inert under normal environmental conditions, does not typically react to form green-colored compounds. However, when gold is alloyed with metals such as copper or silver to increase its durability or alter its color, these less noble metals are susceptible to oxidation and corrosion. This corrosion can produce a greenish film on the surface. For example, if a gold ring contains a significant proportion of copper, prolonged exposure to moisture or certain chemicals can lead to the formation of copper carbonates, which exhibit a greenish color.
Understanding the potential for color change in gold alloys is crucial for maintaining the aesthetic value and longevity of gold items. Historically, goldsmiths have been aware of the varying reactivity of different metals and have adjusted alloy compositions to mitigate the risk of discoloration. The perceived purity and value of a gold object are intrinsically linked to its resistance to tarnish. Furthermore, the presence of green discoloration can indicate the presence of base metals and potentially devalue the item. Recognizing the underlying causes enables proper cleaning and care procedures that prevent or reverse such color changes.